1991 - JAMB Chemistry Past Questions and Answers - page 3

21
What volume of CO2 at s.t.p would be obtained by reacting trioxocarbonate (IV) with excess acid?

(G.M.V at s.t.p = 22.4 dm3)
A
2.240 cm 3
B
22.40 cm 3
C
224.0 cm 3
D
2240 cm 3
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22
If a current of 1.5 A is passed for 4.00 hours through a molten tin salt and 13.3g of tin is deposited, what is the oxidation state of the metal in the salt?

(Sn = 118.7, F = 96500 C mol-1)
A
1
B
2
C
3
D
4
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23
Which of the following equimolar solutions, Na2CO3 Na2 SO
4CI FeCI3 CH3COONa,
have pH greater than 7?
A
FeCI 3 and NH 4CI
B
Na2CO3, CH3COONa and Na,Na2SO4
C
Na2CO3 and CH3COONa
D
FeCI3, CH3COONa and NH4CI
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24
MnO-4 + 8H+ + ne → Mn++ + 4H2O. Which is the value of n in the reaction above?
A
2
B
3
C
4
D
5
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25
2H2S(g) + SO2(g) → 3S(s) + 2H2O(I). The above reaction is?
A
a redox reaction H2S is the oxidant and SO2 is the reductant
B
a redox reaction in which SO2 is the oxidant and H2S is the reductant
C
not a redox reaction because there is no oxidant in reaction equation
D
not a redox because there is no reductant in the reaction equation
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26
Magnesium (IV) oxide is known to hasten the decomposition of hydrogen peroxide. Its main action is to?
A
increase the surface area of the reactants
B
increase the concntration of the reactants
C
lower the activation energy for the reaction
D
lower the heat of reaction, ∆H, for the reaction
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27
1.1 g of CaCI2 dissolved in 50 cm3 of water caused a rise in temperature of3.4°C. The heat of reaction, ∆H for CaCI2 in kj per mole is?

(Ca = 40, CI = 35.5, specific heat of water is 4.18 jk-1
A
-71.1
B
-4.18
C
+71.1
D
+111.0
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28
NO(g) + CO(g) ↔ (1)/(2)N2(g) + CO2(g) ∆H = -89.3 kj.
What conditions would favour maximum conversion of nitrogen (II) oxide and carbon (II) oxide in the reaction above?
A
Low temperature and high pressure
B
High temperature and low pressure
C
High temperature and high pressure
D
Low temperature and low pressure
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29
Which of the following equilibria is unaffected by a pressure change?
A
2NaCI(s) ↔ 2Na (I) + CI2(g)
B
H 2(g) + I2(g) ↔ 2HI(g)
C
2O3(g) ↔ 3O2(g)
D
2NO2(g) ↔ N2O4(g)
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30
Which of the following gases will rekindle a brightly glowing splint?
A
NO2
B
NO
C
N2O
D
CI2
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