1992 - JAMB Chemistry Past Questions and Answers - page 3

21
Calculate the mass, in kilograms, of magnesium produced by the electrolysis of magnesium (II) chloride in a cell operating for 24 hours at 500 amperes.
A
2.7
B
5.4
C
10.8
D
21.7
correct option: b
Mg + 2e → 24 gms
2f → 24 gms
2 x 96,500 → 24 gms
Q = (500 x 1440 x 60)
Q = 4320000 C
1 mole of mg = (1) / (2 x 96,500) x (43200000) / (1)
= (24)/(1) = (1036800000) / (193000) = 5372.020725 gms
in leg = (5372.020725) / (1000) = 5.4 leg
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22
S2O2-3 + I2 → S2O62- + 2I-. In reaction above, the oxidizing agent is?
A
S2O32-
B
I2
C
S4O62-
D
I-
correct option: b
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23
MnO2 + 2CI- + 4H+ → MnO2+ + CI2 + 2H2O.
The changes is oxidation numbers when the manganese, chloride and hydrogen ions react according to the above equation are respectively?
A
2, 2, 4
B
-1, -2, 4
C
-2, 1, 0
D
2, 4, 0
correct option: c
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24
In which of the following is the entropy change positive?
A
H2O(I) → H2O(g)
B
Cu2+(aq) + Fe(s) → Fe(2+) + Cu(s)
C
N2(g) + 3H2(g) → 2NH3(g)
D
2HCI(s) → H2(g) + CI2(g)
correct option: a
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25
In what way is equilibrium constant for the forward reaction related to that of the reversed reaction?
A
The additional of the two is expected to be one
B
The product of the two is expected to be one
C
The two equilibrium constants are identical
D
The product of the two is always greater than one
correct option: a
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26
Which of the following equilibria shows little or no net reaction when the volume of the system is decreased?
A
H2(g) + I2(g) ≈ 2HI(g)
B
2NO2(g) ≈ N2O4(g)O4(g)N2O4(g)
C
PCI5(g) ≈ PCI3(g) + CI2(g)
D
ZnO(s) + CO2(g) ≈ ZnCO3(g)
correct option: d
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27
For a general equation of the nature xP + yQ ≈ mR + nS, the expression for the equilibrium constant is?
A
k (p)x (Q)y
B
(p)x (Q)y / (R)m (S)n
C
(R)m (S)n / (p)x (Q)y
D
m(R) n (S) / x(P) y (Q)
correct option: c
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28
Which of these statements is TRUE about carbon (IV) oxide?
A
it supports combustion
B
It is strongly acidic in water
C
It is very soluble in water
D
It supports the buring of magnesium to produce magnesium oxide
correct option: c
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29
Which of the following combination of gases is used for metal welding? i. Oxygen and ethyne, ii. Hydrogen and ethyne, iii. Hydrogen and oxygen, iv. Ethyne, hydrogen and oxygen.
A
i and ii
B
ii and iv
C
i and iii
D
ii and iv
correct option: a
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30
Which of the following oxides of nitrogen is unstable in air?
A
NO2
B
NO
C
N2O4
D
N2O5-
correct option: b
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