Energy Changes in Chemical Reactions - SS1 Chemistry Past Questions and Answers - page 2
Define exothermic and endothermic reactions and discuss their differences in terms of energy transfer and the direction of heat flow.
Exothermic and endothermic reactions are two types of chemical reactions that differ in terms of energy transfer and the direction of heat flow.
- Exothermic reactions: Exothermic reactions release energy in the form of heat to the surroundings. In these reactions, the energy of the products is lower than the energy of the reactants, resulting in a net release of energy. The heat flow is from the system (reactants) to the surroundings. Examples of exothermic reactions include:
- Combustion reactions: When a substance reacts with oxygen to produce carbon dioxide and water, such as the combustion of gasoline or the burning of wood.
- Neutralisation reactions: The reaction between an acid and a base to form water and a salt, such as the reaction between hydrochloric acid (HCl) and sodium hydroxide (NaOH) to produce water (H2O) and sodium chloride (NaCl).
- Some oxidation reactions: For example, the reaction between iron (Fe) and oxygen (O2) to form iron(III) oxide (Fe2O3) in the process of rusting.
- Endothermic reactions: Endothermic reactions absorb energy from the surroundings. In these reactions, the energy of the products is higher than the energy of the reactants, resulting in a net absorption of energy. The heat flow is from the surroundings to the system. Examples of endothermic reactions include:
- Dissolving certain salts in water: For example, the dissolution of ammonium nitrate (NH4NO3) in water.
- Photosynthesis: The process by which plants convert carbon dioxide (CO2) and water (H2O) into glucose and oxygen (O2) using energy from sunlight.
- Some decomposition reactions: For example, the thermal decomposition of calcium carbonate (CaCO3) to form calcium oxide (CaO) and carbon dioxide (CO2) requires an input of heat.
Discuss the importance of exothermic and endothermic reactions in everyday life and provide examples of their applications.
Exothermic and endothermic reactions have significant importance in various aspects of everyday life and find numerous applications. Their distinct energy characteristics allow for diverse applications in different fields.
- Importance of exothermic reactions:
Exothermic reactions have several important applications, including:
- Energy production: Many energy production processes, such as combustion in power plants and the burning of fossil fuels, are based on exothermic reactions. These reactions release large amounts of heat energy, which can be harnessed for electricity generation, heating, and other energy needs.
- Heating and cooking: Combustion reactions, such as burning natural gas or wood, provide heat energy for heating homes and cooking food.
- Industrial processes: Exothermic reactions are widely used in various industrial processes. For example, in the production of cement, the exothermic reaction between calcium oxide (CaO) and water (H2O) generates heat, aiding in the curing and hardening of the cement mixture.
- Chemical synthesis: Exothermic reactions are often utilised in chemical synthesis to drive reactions forward and produce desired products. For instance, the Haber-Bosch process, which is used to produce ammonia (NH3) from nitrogen (N2) and hydrogen (H2), is an exothermic reaction that releases heat.
- Importance of endothermic reactions:
Endothermic reactions also have important applications in various fields, including:
- Cooling systems: Endothermic reactions are employed in cooling systems, such as refrigerators and air conditioners. These systems utilise the absorption of heat energy from the surroundings to cool the interior.
- Cold packs and instant cold therapy: Endothermic reactions can be utilised in cold packs or instant cold therapy products. The reaction between chemicals, such as ammonium nitrate and water, absorbs heat from the surroundings, resulting in a drop in temperature and providing a cooling effect.
- Cooking processes: Certain cooking techniques, such as baking, rely on endothermic reactions. For example, as the dough undergoes endothermic reactions during baking, heat is absorbed from the surroundings, causing the dough to rise and bake.
- Sports and recreation: Endothermic reactions find applications in sports and recreation. Cold packs or instant ice packs are used for first aid in cases of injury to reduce swelling and provide pain relief.
Which of the following statements about enthalpy change is correct?
Enthalpy change is the change in internal energy of a system.
.
Enthalpy change is the change in pressure of a system.
Enthalpy change is the heat absorbed or released during a chemical reaction.
Enthalpy change is the change in temperature of a system
Which of the following units is used to measure enthalpy change?
Kelvin (K)
Joule (J)
Pascal (Pa)
Gram (g)
Calorimetry is the science of measuring:
Enthalpy changes
Temperature changes
Pressure changes
Volume changes
Which of the following devices is commonly used in calorimetry experiments?
Thermometer
Bunsen burner
Spectrophotometer
Bomb calorimeter
In an exothermic reaction, the enthalpy change is:
Positive
Negative
Zero
It depends on the reaction conditions
The enthalpy change for a reaction can be determined using which equation?
q = mcΔT
H = mcΔT
ΔH = q/m
ΔH = mc
Hess's law is based on the principle of:
Conservation of energy
Conservation of mass
Conservation of momentum
Conservation of volume
Enthalpy change can be determined experimentally by measuring the:
Initial temperature of the system
Final temperature of the system
Heat capacity of the calorimeter
Temperature change of the system