Energy Changes in Chemical Reactions - SS1 Chemistry Past Questions and Answers - page 4

31

Define heat of formation and explain how it is related to enthalpy changes and Hess's Law.

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32

Which of the following best defines spontaneity in a chemical reaction?

 

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A

The reaction occurs rapidly.

 

B

The reaction occurs without any external influence.

 

C

The reaction occurs with a decrease in entropy.

 

D

The reaction occurs at a constant temperature.

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33

Spontaneous reactions are characterised by:

 

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A

 A positive change in Gibbs free energy (ΔG).

 

B

A negative change in Gibbs free energy (ΔG).

 

C

A zero change in Gibbs free energy (ΔG).

 

D

An unpredictable change in Gibbs free energy (ΔG).

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34

Which of the following statements is true regarding the Gibbs free energy (ΔG) of a spontaneous reaction?

 

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A

ΔG is always positive.

 

B

ΔG is always negative.

 

C

ΔG can be positive or negative depending on the reaction conditions.

 

D

ΔG is always zero.

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35

The relationship between the change in Gibbs free energy (ΔG), enthalpy change (ΔH), and entropy change (ΔS) is given by:

 

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A

ΔG = ΔH + ΔS

 

B

ΔG = ΔH - ΔS

 

C

ΔG = ΔH/ΔS

 

D

ΔG = ΔS/ΔH

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36

Which of the following conditions indicates that a reaction is spontaneous at all temperatures?

 

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A

ΔH > 0 and ΔS > 0

 

B

ΔH < 0 and ΔS < 0

 

C

ΔH > 0 and ΔS < 0

 

D

ΔH < 0 and ΔS > 0

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37

The spontaneity of a reaction can be determined by:

 

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A

The initial concentrations of reactants.

 

B

The activation energy of the reaction.

 

C

The sign of ΔG.

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38

At equilibrium, the value of ΔG for a reaction is:

 

 

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B

Negative

 

C

Zero

 

D

Cannot be determined

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39

Which of the following conditions indicates a non-spontaneous reaction?

 

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A

ΔG = 0

 

B

ΔG < 0

 

C

ΔG > 0

 

D

ΔG is not defined for non-spontaneous reactions.

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40

The spontaneity of a reaction can be determined by comparing:

 

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A

Activation energy with enthalpy change.

 

B

Enthalpy changes with entropy change.

 

C

Gibbs free energy change with activation energy.

 

D

Entropy changes with activation energy.

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