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Consider the equation below Cr 2 O 7 2- 6Fe 2 1... - JAMB Chemistry 2019 Question

Consider the equation below:

Cr\(_2\)O\(_7 ^{2-}\) + 6Fe\(^{2+}\) + 14H\(^{+}\) \(\to\) 2Cr\(^{3+}\) + 6Fe\(^{3+}\) + 7H\(_2\)O.

The oxidation number of chromium changes from

A

+5 to +3

B

+6 to +3

C

-2 to +3

D

+7 to +3

correct option: b

Cr\(_2\)O\(_7 ^{2-}\) + 6Fe\(^{2+}\) + 14H\(^{+}\) \(\to\) 2Cr\(^{3+}\) + 6Fe\(^{3+}\) + 7H\(_2\)O

Oxidation of Cr in Cr\(_2\)O\(_7 ^{2-}\) :

Let oxidation of Cr = x

then,

2x + (-2 x 7) = -2 \(\implies\) 2x - 14 = -2

2x = 12 ; x = +6

Therefore,

the change in the oxidation of Cr = +6 to +3

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