Question on: SS3 Chemistry - Chemical Thermodynamics
Consider the reaction: 2A + B ⇌ 3C + D
The standard Gibbs free energy change (ΔG°) for the reaction is -20.0 kJ/mol at 298 K. Calculate the equilibrium constant (K) for the reaction at this temperature
The relationship between the standard Gibbs free energy change (ΔG°) and the equilibrium constant (K) for a reaction at a given temperature (T) is given by the equation:
ΔG° = -RT ln(K)
where R is the gas constant (8.314 J/(mol·K)) and T is the temperature in Kelvin.
Given ΔG° = -20.0 kJ/mol and T = 298 K, we need to convert ΔG° to J/mol:
ΔG° = -20.0 kJ/mol × 1000 J/1 kJ = -20,000 J/mol
Now, we can calculate the equilibrium constant (K):
K = e(-ΔG° / (RT))
K = e^(-(-20,000 J/mol) / (8.314 J/(mol·K) × 298 K))
K = e^(67.94)
K ≈ 9.42 × 1029
Therefore, the equilibrium constant (K) for the reaction at 298 K is approximately 9.42 × 1029.
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