Use the given thermochemical equations to calcu... - SS3 Chemistry Chemical Thermodynamics Question
Use the given thermochemical equations to calculate the enthalpy change for the reaction:
C(s) + 2H2(g) → CH4(g)
given the following data:
1. H2(g) → 2H(g) ΔH = 436.6 kJ/mol
2. C(s) + 2H(g) → CH4(g) ΔH = -74.8 kJ/mol
To find the enthalpy change for the target reaction, we can manipulate the given equations and add them to obtain the desired equation:
1. H2(g) → 2H(g) ΔH = 436.6 kJ/mol (Given)
2. C(s) + 2H(g) → CH4(g) ΔH = -74.8 kJ/mol (Given)
To make the coefficients of H2 match in both equations, we can multiply Equation 2 by 2:
3. 2C(s) + 4H(g) → 2CH4(g) ΔH = -149.6 kJ/mol (Multiply Equation 2 by 2)
Now, add equations 1 and 3 to get the target reaction:
4. H2(g) + 2C(s) + 4H(g) → 2CH4(g) + 2H(g)
Now, add the enthalpy changes of the equations to find the enthalpy change for the target reaction:
ΔHtarget = ΔH1 + ΔH3
ΔHtarget = 436.6 kJ/mol - 149.6 kJ/mol
ΔHtarget = 287.0 kJ/mol
Therefore, the enthalpy change for the reaction: C(s) + 2H2(g) → CH4(g) is 287.0 kJ/mol.
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