What is the empirical formula of a compound con... - JAMB Chemistry 2023 Question
What is the empirical formula of a compound containing 40.00% carbon, 6.67% hydrogen, and 53.33% oxygen by mass?
C\(_4\)H\(_8\)O\(_4\)
CH\(_2\)O
C\(_2\)H\(_4\)O\(_2\)
C\(_3\)H\(_6\)O\(_3\)
To determine the empirical formula, we need to find the simplest whole-number ratio of the atoms in the compound.
Let's assume we have 100 grams of the compound to make percentage to mass conversions easier.
- Carbon: \(40.00\% \rightarrow 40.00 \, \text{g}\)
- Hydrogen: \(6.67\% \rightarrow 6.67 \, \text{g}\)
- Oxygen: \(53.33\% \rightarrow 53.33 \, \text{g}\)
Next, we need to find the mole ratios by dividing each mass by the molar mass of the respective element.
- Moles of Carbon: \(\frac{40.00 \, \text{g}}{12.01 \, \text{g/mol}} \approx 3.33\)
- Moles of Hydrogen: \(\frac{6.67 \, \text{g}}{1.01 \, \text{g/mol}} \approx 6.60\)
- Moles of Oxygen: \(\frac{53.33 \, \text{g}}{16.00 \, \text{g/mol}} \approx 3.33\)
Now, we find the simplest whole-number ratio by dividing each mole value by the smallest of the three:
- Carbon: \(\frac{3.33}{3.33} \approx 1\)
- Hydrogen: \(\frac{6.60}{3.33} \approx 2\)
- Oxygen: \(\frac{3.33}{3.33} \approx 1\)
The ratio is \(1:2:1\), suggesting the empirical formula is \(CH_2O\).
Therefore, the correct answer is: CH₂O
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