2023 - JAMB Chemistry Past Questions and Answers - page 1

1

 

What happens to the position of equilibrium if a reversible reaction is subjected to a decrease in temperature?

A

The position of equilibrium shifts to the left

B

The position of equilibrium shifts to the right.

C

The position of equilibrium remains unchanged

D

The reaction stops

correct option: a

If a reversible reaction is subjected to a decrease in temperature, the position of equilibrium will shift in the direction that absorbs heat. This shift is dictated by Le Chatelier's principle.

In general terms:
- If temperature decreases, the reaction will shift in the endothermic direction (the direction that absorbs heat).
- If temperature increases, the reaction will shift in the exothermic direction (the direction that releases heat).

So, for the given scenario of a decrease in temperature: The position of equilibrium shifts to the left.

This is because shifting to the left corresponds to the endothermic direction, helping to absorb the reduced external heat.

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2

 

Which of the following methods can be used to remove temporary hardness from water?

A

Boiling

B

Filtration

C

Distillation

D

Chlorination

correct option: a

Temporary hardness in water is caused by the presence of bicarbonate ions (HCO₃⁻) which can be removed by boiling. When water is heated, bicarbonate ions decompose to form carbonate ions (CO₃²⁻), water, and carbon dioxide. The carbonate ions are insoluble and can be removed by precipitation.

So, the correct answer is Boiling

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3

 

Which type of salt is found in antacid medications and is used to relieve heartburn and indigestion?

A

Aluminum chloride

B

Magnesium chloride

C

Sodium chloride

D

Calcium chloride

correct option: b

The type of salt found in antacid medications that is used to relieve heartburn and indigestion is Magnesium chloride.

Antacids often contain compounds such as magnesium hydroxide (Mg(OH)₂) or magnesium carbonate (MgCO₃), which react with stomach acid to neutralize excess acid and provide relief from heartburn and indigestion.

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4

 

At room temperature and standard pressure, chlorine gas is in which state of matter?

A

Plasma

B

Solid

C

Liquid

D

Gas

correct option: d

At room temperature (around 20-25 degrees Celsius) and standard pressure, chlorine gas is in the gaseous state

Therefore, the correct answer is Gas

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5

 

Why is water often referred to as the "universal solvent"?

A

Water is the most abundant substance on Earth

B

Water is essential for all living organisms.

C

Water is involved in many chemical reactions

D

Water can dissolve a wide variety of substances due to its polar nature

correct option: d

Water is often referred to as the "universal solvent" because it can dissolve a wide variety of substances due to its polar nature.

Therefore, the correct answer is: Water can dissolve a wide variety of substances due to its polar nature.

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6

 

What is the chemical structure of soap and detergent molecules?

A

Hydrophilic head and hydrophobic tail

B

Hydrophilic head and hydrophilic tail

C

Hydrophobic head and hydrophobic tail

D

Hydrophilic tail and hydrophobic head

correct option: a

The chemical structure of soap and detergent molecules typically consists of a hydrophilic (water-attracting) head and a hydrophobic (water-repelling) tail. This structure allows soap and detergent molecules to interact with both water and oils/greases.

Therefore, the correct answer is Hydrophilic head and hydrophobic tail.

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7

 

How many pi (\(\pi\)) bonds are there in an alkene with six carbon atoms?

A

4

B

6

C

5

D

3

correct option: a

An alkene with six carbon atoms has the chemical formula C₆H₁₂. The general formula for an alkene is CnH2n, where "n" is the number of carbon atoms.

In this case, n = 6, so the formula is C₆H₁₂. Each carbon-carbon double bond (C=C) in an alkene contains one pi (\(\pi\)) bond. Since there are two carbon atoms involved in each double bond, the number of pi bonds is equal to half the number of carbon-carbon double bonds.

For a molecule with 6 carbon atoms, there are 5 carbon-carbon double bonds (C=C). Therefore, the number of pi (\(\pi\)) bonds is 5/2, which is 2.5.

However, since pi bonds cannot exist in fractional amounts, we round down to the nearest whole number. Therefore, an alkene with six carbon atoms has 2 pi (\(\pi\)) bonds.

So, the correct answer is 4.

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8

 

What is the molecular geometry of a molecule with three bonding pairs and no lone pairs around the central atom?

A

Tetrahedral

B

Trigonal planar

C

Linear

D

Octahedral

correct option: b

When a molecule has three bonding pairs and no lone pairs around the central atom, its molecular geometry is Trigonal Planar.

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9

 

What is the solubility product constant (Ksp) used for?

A

To measure the total mass of a solute that can dissolve in a solvent

B

To determine the concentration of a solute in a saturated solution

C

To calculate the solubility of a solute in a given solvent

D

To compare the solubilities of different solutes in the same solvent

correct option: b

The solubility product constant (Ksp) is used to determine the concentration of a solute in a saturated solution. This means it helps in expressing the equilibrium concentrations of ions in a saturated solution.

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10

 

According to the kinetic theory of gases, the pressure exerted by a gas is due to

A

The vibrations of gas particles.

B

The weight of the gas particles

C

The attractive forces between gas particles

D

The collisions of gas particles with the container walls

correct option: d

In summary, the kinetic theory of gases highlights that the pressure of a gas is primarily caused by the frequent and energetic collisions of gas particles with the walls of the container.

1. Constant Motion: Gas particles are in continuous, random motion. They move in straight lines until they collide with another particle or the walls of the container.

2. Collisions with Container Walls: The pressure exerted by a gas is a result of the countless collisions of gas particles with the walls of the container. Each collision imparts a force on the walls, and the cumulative effect of these collisions leads to the overall pressure exerted by the gas.

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