2022 - JAMB Chemistry Past Questions and Answers - page 3

21

Crude petroleum is converted to useful products by the process of?

A

fractional crystallization

B

fractional distillation

C

filtration

D

chromatography

correct option: b

Fractional distillation is a process used in crude oil refineries to separate (as well as join or split) the various lengths of hydrocarbon chains to create different petroleum products from the different distillates. More.

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22

An organic compound contains 69% carbon, 15.3% hydrogen and 30.7% oxygen. Calculate the the empirical formula [C=12, H = 1, O = 16]

A

C\(_4\)H\(_12\)O

B

C\(_3\)H\(_9\)O

C

C\(_4\)H\(_9\)O

D

C\(_3\)H\(_8\)O

correct option: d

C  \(\frac{69}{12}\)   H  \(\frac{15.3}{1}\)     O  \(\frac{30.7}{16}\)

C = 5.75
H = 15.3
O = 1.92

C \(\frac{5.75}{1,92}\)    H  \(\frac{15.3}{1.92}\)     O  \(\frac{1.92}{1.92}\)

C\(_3\)H\(_8\)O

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23

2H\(_2\) + O\(_2\) → 2H\(_2\)O

From the equation above, calculate the volume of unreacted oxygen gas if a mixture of 50cm\(^3\) of hydrogen and 75cm\(^3\) of oxygen is involved

A

85cm\(^3\)

B

50cm\(^3\)

C

125cm\(^3\)

D

55cm\(^3\)

correct option: b

From the given equation, 2 mol H\(_2\) reacted with 1 mol of O\(_2\)

50cm\(^3\) hydrogen reacted with 25cm\(^3\) oxygen

remainder oxygen = supplied amount - reacted amount 

=> 75cm\(^3\) - 25cm\(^3\)

= 50cm\(^3\)

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24

In which of the following will hydrogen form an ionic compound? 

A

HCL

B

NaH

C

NH\(_3\)

D

CH\(_4\)

correct option: b

NaH ionic hydride which is also known as saline (salt-like) hydride, composed of Na+ and H− ions

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25

If the volume of a given mass of a gas at 0ºc is 29.5cm\(^3\). What will be the volume of the gas at 15ºc, given that the pressure remains constant?

A

31.6

B

62.2

C

32.7

D

31.1

correct option: d

Charles' law states that the volume occupied by a fixed amount of gas is directly proportional to its absolute temperature if the pressure remains constant.

Given that:
V\(_1\) = 29.5cm\(^3\)
V\(_2\) = ?
T\(_1\) = 0ºc or 273k
T\(_2\) = 15ºc or 288k

\(\frac{V_1}{T_1}\) = \(\frac{V_2}{T_2}\)

V\(_2\) = \(\frac{V_1 x T_2}{T_1}\) 

=> \(\frac{29.5 x 288}{273}\)

V\(_2\) = 31.1cm\(^3\)

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26

The reactions below represent neutralization reactions, in which of them is the value of ΔH highest?

A

CH\(_3\)CH\(_2\)COOH + KOH → CH\(_3\)CH\(_2\)COOK + H\(_2\)O

B

NH\(_4\)OH + HCL → NH\(_4\) + H\(_2\)O

C

NaOH + HCL → NaCL + H\(_2\)O

D

CH\(_3\)COOH + NaOH → CH\(_3\)COONa + H\(_2\)O

correct option: c

Enthalpy changes of neutralization are always negative - heat is released from the reaction of an acid and an alkali.

Such enthalpy changes are smaller in magnitude compared to that between the reaction of strong acids and strong bases.

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27

The pollutant that is usually present in a city which generates its electricity from coal?

A

fog

B

carbon(ii)oxide

C

smog

D

sulphur(iv)oxide

correct option: d

Sulfur, due to the burning of coal in the process of generating electricity.

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28

The dehydration of CH\(_3\)CH\(_2\)CH\(_2\)CH\(_2\)OH will give?

A

HC≡CCH\(_2\)CH\(_3\)

B

CH\(_2\)≡CH\(_2\)CH\(_3\)

C

CH\(_3\)C≡CCH\(_3\)

D

CH\(_3\)CH=CHCH\(_3\)

correct option: d

An alkene is produced when dehydration of alcohol is performed in which alcohol, upon reaction with protic acids, loses a molecule of water to form alkenes.

Such a reaction is an elimination reaction.

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29

When heat is absorbed during a chemical reaction, the reaction is said to be ___

A

thermodynamic

B

exothermic

C

isothermal

D

endothermic

correct option: d

An endothermic reaction is a chemical reaction in which heat is absorbed from its environment hence resulting in an increase in the enthalpy H of the system.

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30

Which of the following best represents a solid gas mixture?

A

milk

B

kerosene

C

soil

D

smoke

correct option: d

Examples of solids in gas mixture:

  • smoke
  • ice clouds
  • dust

Examples of liquid in gas mixture:

  • fog
  • mist
  • vapour
  • hair sprays

Examples of gas in solid mixture:

  • aerogel
  • styrofoam.
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