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Analytical Chemistry I: Qualitative Analysis - SS3 Chemistry Past Questions and Answers - page 3

21

A mixture of oil and water can be separated using which technique?

 

A

Filtration

 

B

Decantation

 

C

Distillation

 

D

Emulsification

correct option: b
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22

Which separation technique is commonly used in the purification of alcohol?

 

A

Filtration

 

B

Evaporation

 

C

Distillation

 

D

Chromatography

correct option: c
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23

What separation technique is based on the principle of differences in solubility between components in a mixture?

 

A

Filtration

 

B

Distillation

 

C

Evaporation

 

D

Chromatography

correct option: d
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24

A mixture of iron filings and sulphur can be separated using a magnet. What property of iron allows it to be separated from sulphur using this method?

 

A

Iron is magnetic

 

B

Iron has a higher density than sulphur

 

C

Iron reacts with sulphur

 

D

Iron is soluble in water

correct option: a
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25

Discuss the principles and applications of filtration as a separation technique. Provide examples of how filtration is used in various industries and research fields.

Filtration is a separation technique that relies on a porous barrier to separate solid particles from a liquid or gas based on particle size. The principle behind filtration is that smaller particles pass through the pores of the filter, while larger particles are retained, leading to the separation of the mixture. Filtration is widely used in industries and research fields for various purposes.

In the pharmaceutical industry, filtration is a crucial step in the production of drugs and medicines. It is used to remove impurities, separate crystals, and sterilise liquids. For example, during the manufacturing of antibiotics, filtration is employed to remove microbial contaminants, ensuring the final product is safe for consumption.

In environmental science and water treatment, filtration plays a vital role in purifying drinking water and wastewater. Large-scale filtration systems are used to remove suspended particles, sediments, and microorganisms, making water safe for human use and minimising environmental impacts.

Laboratories use filtration in research and analysis processes. For instance, in chemical analysis, filtration is utilised to separate a solid precipitate from a liquid solution after a chemical reaction. This enables researchers to isolate and study the solid compound further.

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26

Describe the principles and applications of evaporation as a separation technique. Provide examples of how evaporation is used in different scientific and industrial settings.

Evaporation is a separation technique that involves the conversion of a liquid into its vapour phase, leaving behind solid solutes or concentrated solutions. The principle behind evaporation is the application of heat to increase the vapour pressure of the liquid, allowing molecules to escape from the liquid phase into the gas phase. The remaining substances become more concentrated as the liquid volume decreases.

Evaporation finds widespread applications in various scientific and industrial settings:

1.    Salt Production: In the salt industry, seawater is collected in large shallow ponds. The sun's heat causes the water to evaporate, leaving behind crystallised salt, which is then harvested.

2.    Food Processing: Evaporation is utilised in the food industry to concentrate liquid products like fruit juices and dairy. By evaporating water, the desired compounds become more concentrated, leading to higher quality and longer shelf life.

3.    Separation of Solvents: In laboratories and chemical industries, evaporation is employed to separate solvents from dissolved substances. For instance, after a chemical reaction, a chemist may use rotary evaporators to remove the solvent and obtain the desired compound.

4.    Desalination: In some regions, where freshwater is scarce, evaporation is part of the desalination process. Seawater is evaporated to leave the salts behind, and the condensed vapour is collected as freshwater.

5.    Effluent Treatment: Evaporation is used in the treatment of industrial effluents to concentrate the pollutants for further processing or disposal.

6.    Cooling Systems: Evaporative cooling systems use the principle of evaporation to cool down the air, commonly seen in air conditioners or cooling towers.

In conclusion, evaporation is a versatile separation technique widely used in industries ranging from food processing to environmental remediation. Its ability to concentrate solutions and separate solvents makes it an essential process in various scientific and industrial applications.

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27

In the identification of cations in an unknown sample using qualitative analysis, which reagent is commonly used to test for the presence of Group 2 metal cations (calcium, strontium, and barium)?

A

Silver nitrate (AgNO3)

 

B

Sodium hydroxide (NaOH)

 

C

Ammonium carbonate ((NH4)2CO3)

 

D

Sodium sulphate (Na2SO4)

correct option: b
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28

When testing an unknown sample for the presence of sulphate ions (SO4^2-), which reagent is added to produce a white precipitate if sulphates are present?

 

A

Silver nitrate (AgNO3)

 

B

Barium chloride (BaCl2)

 

C

Ammonium hydroxide (NH4OH)

 

D

Sodium carbonate (Na2CO3)

correct option: b
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29

Which of the following cations gives a brick-red flame colouration when a sample is heated on a platinum wire loop in the flame test?

 

A

Sodium (Na+)

 

B

Potassium (K+)

 

C

Calcium (Ca2+)

 

D

Copper (Cu2+)

correct option: d
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30

During the anion analysis of an unknown sample, a white precipitate forms when adding silver nitrate (AgNO3) reagent. Subsequently, the precipitate is insoluble in dilute nitric acid. Which anion is most likely present in the sample?

 

A

Chloride (Cl-)

 

B

Bromide (Br-)

 

C

Iodide (I-)

 

D

Carbonate (CO32-)

correct option: d
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